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Q#1 Solution Thermodynamics GATE CH 2022 NAT +2 marks -0 marks

The molar excess Gibbs free energy (𝑔E ) of a liquid mixture of A and B is given by

                 .

where 𝑥A and 𝑥B are the mole fraction of A and B, respectively, the universal gas constant, 𝑅 = 8.314 J K-1 mol-1, 𝑇 is the temperature in K, and 𝐶1, 𝐶2 are temperature-dependent parameters. At 300 K, 𝐶1 = 0.45 and 𝐶2 = −0.018. If 𝛾A and 𝛾B are the activity coefficients of A and B, respectively, the value of

                                           

at 300 K and 1 bar is _________ (rounded off to the nearest integer).

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