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Q#1 Solution Thermodynamics GATE CH 2024 NAT +2 marks -0 marks

Ethylene obeys the truncated virial equation-of-state

\(\frac{𝑃𝑉}{𝑅𝑇} = 1 +\frac{𝐵𝑃}{RT}\)

where P is the pressure, V is the molar volume, T is the absolute temperature and B is the second virial coefficient. The universal gas constant \(𝑅 = 83.14 bar cm^3 mol^{−1}K^{−1}\)

At 340 K, the slope of the compressibility factor vs. pressure curve is  Let \(G^R\)denote the molar residual Gibbs free energy. At these conditions, the value of 

\(\begin{align*} \left(\frac{\partial G^R}{\partial P}\right)_T \end{align*}\) , in \(cm^3 mol^{-1}\), rounded off to 1 decimal place, is ___________

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